Optical absorption of copper and silver at 4.2°K

Manfred A. Biondi


Measurements of the optical absorption of copper and silver are made over the wavelength range 0.3-3.3μ at a temperature of 4.2°K where the classical mean free path of the conduction electrons is much greater than the depth of penetration of the electromagnetic field. The absorptivity is determined calorimetrically, i.e., from the temperature rise produced in the sample by the absorption of the incident radiation. In the infrared (λ>1.5μ) the absorptivity, A, is found to be independent of wavelength. The measured values, A=0.0050 for copper and A=0.0044 for silver, are in good agreement with the values obtained from theory. These results suggest that the infrared absorptivity results from absorption of photons by conduction electrons (a) during diffuse internal reflection of the electrons from the surface of the metal and (b) during phonon-generating collisions in the skin-depth layer. © 1956 The American Physical Society.

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Materials
Curve 1
Temperature K: 4.2 Wavelength Range, μ: 0.362-0.951 Geometry θ: 15° Composition (weight percent), Specifications and Remarks: OFHC Copper; faced with a diamond cutting tool; mechanically polisbed with metallographic polishing paper and electropolished to remove abrasives in the surface layer; annealed for ~10 hrs either in vacuum or in a hydrogen atmosphere at ~303 K below melting point; electropolished; rinsed in absolute alcohol and boiled distilled water; mounted in the apparatus under a helium atmosphere to prevent oxidation; measured in vacuum.
Curve 1
Temperature K: 4.2 Wavelength Range, μ: 0.365-0.949 Geometry θ: 15° Composition (weight percent), Specifications and Remarks: 99. 98 pure; machined from vacuum melted ingot, faced with a diamond cutting tool, mechanically polished with metallographic polishing paper, electropolished, annealed for ~10 hrs either in vacuum or in hydrogen at -303 K below melting point, electropolished, rinsed, and mounted in the apparatus under a helium atmosphere to prevent oxidation; measured in vacuum.