Band structure of noble metal alloys: Optical absorption in α-brasses at 4.2°K

M. A. Biondi, J. A. Rayne


Calorimetric optical absorption measurements at 4.2°K have been made on a representative series of α brasses over the wavelength range 0.23 to 4.0 microns using electropolished bulk specimens. Changes in the absorption spectrum below 6000 A are interpreted in the light of current theories concerning the band structure of noble metal alloys. The variation of the infrared absorptivity with residual resistivity shows that the impurity relaxation time for copper is anisotropic. This anisotropy increases on alloying and suggests that the Fermi surface becomes more distorted with increasing solute concentration. © 1959 The American Physical Society.

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Materials
Curve 1
Temperature K: 4.2 Wavelength Range, μ: 0.2325-0.6997 Geometry θ: 15° Composition (weight percent), Specifications and Remarks: High-purity copper; cold worked; maintained at 1073 K for 24 hrs; annealed in helium; electropolished and washed; measured in vacuum.
Curve 2
Temperature K: 4.2 Wavelength Range, μ: 0.616-4.004 Geometry θ: 15° Composition (weight percent), Specifications and Remarks: Above specimen and conditions.