H. E. Rast, H. H. Caspers, S. A. Miller
The infrared spectral emittance E of single scrystals of YVO4 has been examined near 4.2 and 77°K in the wavelength range 4-125 μm. Of the expected seven active transverse optical modes at k∼0, six have been observed and assigned to their symmetry species based on their polarization with respect to the crystalline axes. The observed frequencies of the transverse optic Eu modes were 196, 261, and 788 cm-1 and for A2u modes, 310, 455, and 803 cm-1. The relation between emittance and reflectance, E=1-R in the opaque region of lattice vibrations, permits one to determine the reflectance R. By least-square-fitting the reflectance data to an independent set of damped harmonic oscillators, infrared dispersion parameters were determined for the Eu vibrations. © 1968 The American Physical Society.
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| Wavelength / 𝜇m | Emittance / |
|---|---|
| 4.05 | 0.814 |
| 4.0 | 0.832 |
| 5.0 | 0.851 |
| 5.51 | 0.881 |
| 6.27 | 0.912 |
| 6.8 | 0.907 |
| 7.26 | 0.912 |
| 7.42 | 0.927 |
| 7.69 | 0.917 |
| 8.68 | 0.948 |
| 9.51 | 0.964 |
| 10.2 | 0.983 |
| 10.4 | 0.979 |
| 10.5 | 0.958 |
| 10.6 | 0.905 |
| 10.8 | 0.31 |
| 11.0 | 0.149 |
| 11.2 | 0.097 |
| 11.8 | 0.06 |
| 12.3 | 0.071 |
| 12.6 | 0.121 |
| 13.0 | 0.509 |
| 13.4 | 0.62 |
| 14.0 | 0.715 |
| 14.6 | 0.75 |
| 15.6 | 0.788 |
| 17.0 | 0.818 |
| 17.0 | 0.861 |
| 17.1 | 0.82 |
| 18.4 | 0.843 |
| 22.2 | 0.876 |
| Wavelength / 𝜇m | Emittance / |
|---|---|
| 18.8 | 0.833 |
| 19.8 | 0.835 |
| 21.3 | 0.852 |
| 22.9 | 0.857 |
| 24.3 | 0.88 |
| 25.5 | 0.908 |
| 25.7 | 0.88 |
| 26.3 | 0.899 |
| 27.1 | 0.894 |
| 28.0 | 0.922 |
| 28.2 | 0.91 |
| 28.9 | 0.955 |
| 30.2 | 0.968 |
| 31.1 | 0.99 |
| 31.3 | 0.944 |
| 31.5 | 0.888 |
| 31.6 | 0.814 |
| 31.8 | 0.796 |
| 32.1 | 0.873 |
| 32.3 | 0.783 |
| 32.7 | 0.362 |
| 32.9 | 0.255 |
| 33.1 | 0.219 |
| 34.2 | 0.151 |
| 35.0 | 0.11 |
| 36.8 | 0.127 |
| 37.1 | 0.179 |
| 37.4 | 0.268 |
| 38.2 | 0.482 |
| 38.8 | 0.57 |
| 39.4 | 0.619 |
| 40.3 | 0.673 |
| 40.7 | 0.678 |
| 40.8 | 0.706 |
| 41.4 | 0.725 |
| 42.0 | 0.762 |
| 42.7 | 0.774 |
| 43.2 | 0.811 |
| 44.1 | 0.901 |
| 44.7 | 0.919 |
| 45.4 | 0.971 |
| 45.7 | 0.921 |
| 46.4 | 0.405 |
| 46.6 | 0.336 |
| Wavelength / 𝜇m | Emittance / |
|---|---|
| 4.5 | 0.819 |
| 4.5 | 0.841 |
| 4.81 | 0.857 |
| 5.31 | 0.852 |
| 5.8 | 0.881 |
| 6.56 | 0.915 |
| 7.1 | 0.91 |
| 7.58 | 0.928 |
| 7.85 | 0.92 |
| 8.05 | 0.938 |
| 8.41 | 0.932 |
| 9.25 | 0.979 |
| 9.77 | 0.985 |
| 10.3 | 0.99 |
| 10.4 | 0.856 |
| 10.7 | 0.532 |
| 10.8 | 0.245 |
| 10.9 | 0.144 |
| 11.1 | 0.08 |
| 11.7 | 0.039 |
| 12.0 | 0.039 |
| 12.2 | 0.057 |
| 12.6 | 0.246 |
| 12.9 | 0.452 |
| 13.1 | 0.555 |
| 13.3 | 0.602 |
| 13.6 | 0.66 |
| 14.2 | 0.726 |
| 14.8 | 0.781 |
| 15.4 | 0.79 |
| 16.2 | 0.812 |
| 17.3 | 0.818 |
| 18.7 | 0.818 |
| 19.1 | 0.851 |
| 20.3 | 0.856 |
| 20.5 | 0.871 |
| 20.8 | 0.867 |
| 21.6 | 0.884 |
| 22.1 | 0.885 |
| 22.2 | 0.864 |
| 22.6 | 0.86 |
| 22.7 | 0.878 |
| Wavelength / 𝜇m | Emittance / |
|---|---|
| 18.9 | 0.846 |
| 20.5 | 0.861 |
| 21.7 | 0.894 |
| 22.2 | 0.867 |
| 23.2 | 0.897 |
| 23.8 | 0.926 |
| 24.0 | 0.91 |
| 25.1 | 0.965 |
| 25.6 | 0.978 |
| 25.9 | 0.957 |
| 26.2 | 0.97 |
| 27.0 | 0.958 |
| 27.3 | 0.914 |
| 27.6 | 0.819 |
| 28.4 | 0.535 |
| 28.8 | 0.487 |
| 29.3 | 0.468 |
| 30.7 | 0.485 |
| 31.2 | 0.492 |
| 31.8 | 0.41 |
| 32.3 | 0.449 |
| 32.6 | 0.248 |
| 32.9 | 0.163 |
| 33.2 | 0.124 |
| 33.7 | 0.101 |
| 34.3 | 0.108 |
| 35.0 | 0.082 |
| 36.5 | 0.09 |
| 37.0 | 0.124 |
| 37.5 | 0.169 |
| 37.8 | 0.262 |
| 38.5 | 0.325 |
| 39.3 | 0.382 |
| 39.5 | 0.409 |
| 40.0 | 0.407 |
| 40.6 | 0.426 |
| 40.7 | 0.445 |
| 41.8 | 0.474 |
| 42.9 | 0.541 |
| 43.1 | 0.532 |
| 44.9 | 0.658 |
| 45.3 | 0.693 |
| 46.0 | 0.474 |
| 46.4 | 0.331 |
| Wavelength / 𝜇m | Reflectance / |
|---|---|
| 4.05 | 0.19 |
| 4.06 | 0.169 |
| 5.0 | 0.152 |
| 5.51 | 0.126 |
| 6.27 | 0.087 |
| 6.8 | 0.096 |
| 7.26 | 0.087 |
| 7.42 | 0.077 |
| 7.69 | 0.09 |
| 8.68 | 0.056 |
| 9.51 | 0.038 |
| 10.2 | 0.021 |
| 10.4 | 0.026 |
| 10.5 | 0.049 |
| 10.6 | 0.101 |
| 10.8 | 0.689 |
| 11.0 | 0.845 |
| 11.2 | 0.9 |
| 11.8 | 0.935 |
| 12.3 | 0.926 |
| 12.6 | 0.88 |
| 13.0 | 0.489 |
| 13.4 | 0.38 |
| 14.0 | 0.286 |
| 14.6 | 0.248 |
| 15.6 | 0.213 |
| 17.0 | 0.185 |
| 17.0 | 0.142 |
| 17.1 | 0.183 |
| 18.4 | 0.16 |
| 22.2 | 0.13 |
| Wavelength / 𝜇m | Reflectance / |
|---|---|
| 18.8 | 0.175 |
| 19.8 | 0.17 |
| 21.3 | 0.159 |
| 22.9 | 0.151 |
| 24.3 | 0.13 |
| 25.5 | 0.097 |
| 25.7 | 0.125 |
| 26.3 | 0.108 |
| 27.1 | 0.113 |
| 28.0 | 0.085 |
| 28.2 | 0.094 |
| 28.9 | 0.048 |
| 30.2 | 0.033 |
| 31.1 | 0.011 |
| 31.3 | 0.048 |
| 31.5 | 0.113 |
| 31.6 | 0.189 |
| 31.8 | 0.203 |
| 32.1 | 0.131 |
| 32.3 | 0.211 |
| 32.7 | 0.647 |
| 32.9 | 0.761 |
| 33.1 | 0.789 |
| 34.2 | 0.862 |
| 35.0 | 0.896 |
| 36.8 | 0.884 |
| 37.1 | 0.836 |
| 37.4 | 0.752 |
| 38.2 | 0.533 |
| 38.8 | 0.437 |
| 39.4 | 0.384 |
| 40.3 | 0.325 |
| 40.7 | 0.33 |
| 40.8 | 0.3 |
| 41.4 | 0.288 |
| 42.0 | 0.243 |
| 42.7 | 0.231 |
| 43.2 | 0.196 |
| 44.1 | 0.109 |
| 44.7 | 0.093 |
| 45.4 | 0.039 |
| 45.7 | 0.081 |
| 46.4 | 0.604 |
| 46.6 | 0.674 |
| Wavelength / 𝜇m | Reflectance / |
|---|---|
| 8.0 | 0.074 |
| 8.1 | 0.057 |
| 8.19 | 0.059 |
| 8.3 | 0.065 |
| 8.38 | 0.072 |
| 8.48 | 0.071 |
| 8.59 | 0.071 |
| 8.68 | 0.068 |
| 8.78 | 0.068 |
| 8.88 | 0.081 |
| 8.98 | 0.041 |
| 9.07 | 0.02 |
| 9.17 | 0.019 |
| 9.28 | 0.02 |
| 9.36 | 0.025 |
| 9.51 | 0.03 |
| 9.57 | 0.017 |
| 9.68 | 0.03 |
| 9.79 | 0.028 |
| 9.88 | 0.026 |
| 9.99 | 0.02 |
| 10.1 | 0.021 |
| 10.2 | 0.021 |
| 10.3 | 0.021 |
| 10.4 | 0.033 |
| 10.5 | 0.036 |
| 10.6 | 0.066 |
| 10.7 | 0.15 |
| 10.8 | 0.344 |
| 10.9 | 0.632 |
| 11.0 | 0.766 |
| 11.1 | 0.806 |
| 11.1 | 0.816 |
| 11.2 | 0.829 |
| 11.3 | 0.865 |
| 11.4 | 0.865 |
| 11.5 | 0.871 |
| 11.6 | 0.878 |
| 11.7 | 0.893 |
| 11.8 | 0.893 |
| 11.9 | 0.897 |
| 12.0 | 0.895 |
| 12.1 | 0.89 |
| 12.2 | 0.881 |
| 12.3 | 0.891 |
| 12.3 | 0.88 |
| 12.5 | 0.86 |
| 12.6 | 0.836 |
| 12.7 | 0.783 |
| 12.8 | 0.681 |
| 12.9 | 0.618 |
| 13.0 | 0.514 |
| 13.0 | 0.468 |
| 13.2 | 0.418 |
| 13.3 | 0.406 |
| 13.4 | 0.352 |
| 13.6 | 0.345 |
| 13.6 | 0.329 |
| 13.7 | 0.32 |
| 13.8 | 0.309 |
| 13.9 | 0.284 |
| 14.0 | 0.279 |
| 14.1 | 0.262 |
| 14.2 | 0.264 |
| 14.3 | 0.243 |
| 14.4 | 0.237 |
| 14.6 | 0.233 |
| 14.6 | 0.211 |
| 14.7 | 0.219 |
| 14.9 | 0.219 |
| 15.1 | 0.204 |
| 15.2 | 0.201 |
| 15.3 | 0.198 |
| 15.5 | 0.189 |
| 15.6 | 0.193 |
| 15.8 | 0.197 |
| 15.9 | 0.175 |
| 16.0 | 0.201 |
| 16.1 | 0.187 |
| 16.3 | 0.2 |
| 16.3 | 0.161 |
| 16.6 | 0.182 |
| 16.7 | 0.16 |
| 17.0 | 0.185 |
| 17.1 | 0.157 |
| 17.4 | 0.174 |
| 17.8 | 0.173 |
| 18.0 | 0.148 |
| 18.1 | 0.156 |
| 18.1 | 0.141 |
| 18.5 | 0.151 |
| 18.7 | 0.145 |
| 18.8 | 0.161 |
| 18.9 | 0.144 |
| 19.2 | 0.176 |
| 19.4 | 0.176 |
| 19.6 | 0.182 |
| 19.9 | 0.157 |
| 20.2 | 0.162 |
| 20.6 | 0.16 |
| 20.8 | 0.164 |
| 20.8 | 0.153 |
| 21.3 | 0.165 |
| 21.3 | 0.155 |
| 22.0 | 0.153 |
| 22.3 | 0.146 |
| 22.6 | 0.155 |
| 22.7 | 0.142 |
| 23.0 | 0.136 |
| 23.4 | 0.144 |
| 23.6 | 0.16 |
| 24.0 | 0.133 |
| 24.1 | 0.144 |
| 24.3 | 0.133 |
| 25.0 | 0.131 |
| 25.0 | 0.1 |
| 25.5 | 0.114 |
| 25.5 | 0.096 |
| 26.0 | 0.115 |
| 26.5 | 0.109 |
| 27.2 | 0.113 |
| 27.7 | 0.089 |
| 27.7 | 0.107 |
| 28.2 | 0.096 |
| 28.2 | 0.068 |
| 29.2 | 0.045 |
| 30.3 | 0.033 |
| 31.3 | 0.021 |
| 31.5 | 0.039 |
| 31.5 | 0.073 |
| 32.4 | 0.132 |
| 31.9 | 0.146 |
| 32.3 | 0.171 |
| 32.1 | 0.171 |
| 32.1 | 0.214 |
| 32.7 | 0.26 |
| 32.8 | 0.489 |
| 32.8 | 0.664 |
| 33.0 | 0.759 |
| 33.2 | 0.796 |
| 33.7 | 0.814 |
| 34.1 | 0.831 |
| 34.6 | 0.852 |
| 34.0 | 0.869 |
| 34.7 | 0.869 |
| 34.7 | 0.884 |
| 34.7 | 0.889 |
| 35.3 | 0.9 |
| 36.0 | 0.918 |
| 36.6 | 0.899 |
| 36.9 | 0.893 |
| 36.8 | 0.86 |
| 37.2 | 0.849 |
| 37.5 | 0.768 |
| 38.0 | 0.719 |
| 37.9 | 0.669 |
| 38.3 | 0.614 |
| 38.3 | 0.587 |
| 38.6 | 0.577 |
| 38.8 | 0.544 |
| 38.9 | 0.518 |
| 39.5 | 0.486 |
| 40.2 | 0.456 |
| 40.7 | 0.426 |
| 40.8 | 0.397 |
| 41.2 | 0.38 |
| 41.8 | 0.348 |
| 42.0 | 0.328 |
| 42.2 | 0.314 |
| 42.2 | 0.288 |
| 42.9 | 0.264 |
| 43.3 | 0.243 |
| 43.3 | 0.221 |
| 43.3 | 0.193 |
| 44.1 | 0.172 |
| 43.9 | 0.138 |
| 44.1 | 0.103 |
| 44.1 | 0.07 |
| 44.1 | 0.042 |
| 44.8 | 0.037 |
| 45.3 | 0.199 |
| 45.5 | 0.346 |
| 45.5 | 0.526 |
| 45.5 | 0.613 |
| 45.7 | 0.662 |
| 45.7 | 0.692 |
| 46.5 | 0.707 |
| 47.4 | 0.741 |
| 48.1 | 0.783 |
| 48.8 | 0.831 |
| 51.0 | 0.835 |
| 52.4 | 0.762 |
| 53.2 | 0.585 |
| 54.6 | 0.436 |
| 55.9 | 0.412 |
| 58.8 | 0.38 |
| 58.1 | 0.363 |
| 61.3 | 0.343 |
| 62.9 | 0.327 |
| 66.7 | 0.327 |
| 66.2 | 0.317 |
| 71.4 | 0.326 |
| 69.9 | 0.312 |
| 69.4 | 0.291 |
| 75.8 | 0.28 |
| 80.6 | 0.28 |
| 79.4 | 0.259 |
| Wavelength / 𝜇m | Reflectance / |
|---|---|
| 4.5 | 0.18 |
| 4.5 | 0.158 |
| 4.81 | 0.143 |
| 5.31 | 0.15 |
| 5.8 | 0.12 |
| 6.56 | 0.083 |
| 7.1 | 0.091 |
| 7.58 | 0.07 |
| 7.35 | 0.08 |
| 8.05 | 0.066 |
| 8.41 | 0.064 |
| 9.25 | 0.025 |
| 9.77 | 0.011 |
| 10.3 | 0.011 |
| 10.4 | 0.144 |
| 10.7 | 0.469 |
| 10.8 | 0.753 |
| 10.9 | 0.858 |
| 11.1 | 0.913 |
| 11.7 | 0.96 |
| 12.0 | 0.967 |
| 12.2 | 0.939 |
| 12.6 | 0.744 |
| 12.9 | 0.546 |
| 13.1 | 0.454 |
| 13.3 | 0.39 |
| 13.6 | 0.338 |
| 14.2 | 0.272 |
| 14.8 | 0.221 |
| 15.4 | 0.208 |
| 16.2 | 0.19 |
| 17.3 | 0.178 |
| 18.7 | 0.186 |
| 19.1 | 0.151 |
| 20.3 | 0.141 |
| 20.5 | 0.125 |
| 20.8 | 0.133 |
| 21.6 | 0.121 |
| 22.1 | 0.117 |
| 22.2 | 0.133 |
| 22.6 | 0.141 |
| 22.7 | 0.126 |
| Wavelength / 𝜇m | Reflectance / |
|---|---|
| 18.9 | 0.159 |
| 20.5 | 0.147 |
| 21.7 | 0.12 |
| 22.2 | 0.144 |
| 23.2 | 0.112 |
| 23.8 | 0.085 |
| 24.0 | 0.101 |
| 25.1 | 0.046 |
| 25.6 | 0.032 |
| 25.9 | 0.052 |
| 26.2 | 0.039 |
| 27.0 | 0.051 |
| 27.3 | 0.096 |
| 27.6 | 0.189 |
| 28.4 | 0.466 |
| 28.8 | 0.516 |
| 29.3 | 0.533 |
| 30.7 | 0.525 |
| 31.2 | 0.517 |
| 31.8 | 0.587 |
| 32.3 | 0.558 |
| 32.6 | 0.758 |
| 32.9 | 0.836 |
| 33.2 | 0.872 |
| 33.7 | 0.897 |
| 34.3 | 0.894 |
| 35.0 | 0.92 |
| 36.5 | 0.914 |
| 37.0 | 0.874 |
| 37.5 | 0.829 |
| 37.8 | 0.746 |
| 38.5 | 0.674 |
| 39.3 | 0.619 |
| 39.5 | 0.597 |
| 40.0 | 0.596 |
| 40.6 | 0.582 |
| 40.7 | 0.554 |
| 41.8 | 0.529 |
| 42.9 | 0.467 |
| 43.1 | 0.473 |
| 44.9 | 0.35 |
| 45.3 | 0.318 |
| 46.0 | 0.53 |
| 46.4 | 0.672 |